B.TechSemester 12024-25Engineering ChemistryBAS102

Engineering Chemistry (BAS102) - AKTU Question Paper 2024-25

B.Tech · Semester 1 · Free PDF Download

This is the official AKTU Engineering Chemistry Previous Year Question Paper for B.Tech Semester 1, academic session 2024-25. Published by Dr. A.P.J. Abdul Kalam Technical University (AKTU/UPTU), Lucknow. Free PDF download — no login required.

Course:B.Tech
Semester:Semester 1
Session:2024-25
University:AKTU / UPTU

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Questions Asked in 2024-25

Engineering Chemistry (BAS102) — extracted question text · 70 marks · 3 Hours

Section AAttempt all questions in brief. 2 x 07 = 14
  • a
    Is it possible to achieve 100% waste-free chemical manufacturin g? If not, what are the limitations?
    AnswerBest answer

    No, completely waste-free chemical manufacturing is practically difficult. Some waste is always produced due to side reactions, incomplete conversion, impurities, separation processes, energy use, and limitations of available technology. Green chemistry aims to minimize waste as much as possible.

  • b
    Why do some cholesteric liquid crystals reflect only certain wa velengths of light while others do not?
    AnswerBest answer

    Cholesteric liquid crystals have a helical molecular arrangement. They selectively reflect light whose wavelength matches the pitch of the helix. Therefore, only certain wavelengths are reflected, while the remaining wavelengths pass through the material.

  • c
    Can a molecule be chiral in one environment but achiral in anot her? Provide a theoretical example
    AnswerBest answer

    Yes. A molecule may become chiral when its molecular motion or conformation is restricted by a particular environment.

    Example: A rapidly rotating substituted biphenyl may behave as achiral in solution, but when rotation is restricted in a rigid medium, stable chiral conformations can form.

  • d
    Can corrosion occur in the vacuum of space? If so, under what conditions?
    AnswerBest answer

    Yes, corrosion can occur in space under certain conditions. Although ordinary electrochemical corrosion is very low in vacuum, materials can still degrade due to atomic oxygen, solar radiation, high-energy particles, and traces of moisture or reactive gases.

  • e
    A dry cell battery loses charge even when not in use. What fund amental chemical processes lead to its slow degradation?
    AnswerBest answer

    A dry cell loses charge due to self-discharge. Slow internal redox reactions continue even when the battery is not connected to a circuit.

    These unwanted reactions gradually consume the active materials of the electrodes and electrolyte, causing loss of stored chemical energy.

  • f
    Which type of water contaminatio n- chemical or microbial- is mo re difficult to remove? Justify your answer
    AnswerBest answer

    Chemical contamination is generally more difficult to remove because many dissolved chemicals, such as heavy metals, salts, pesticides, and toxic organic compounds, cannot be removed by simple filtration or disinfection.

    They often require special methods such as adsorption, ion exchange, reverse osmosis, or chemical treatment.

  • g
    Why can thermosetting polymers not be reshaped upon heating, wh ile thermoplastic polymers can?
    AnswerBest answer

    Thermosetting polymers have a highly cross-linked three-dimensional network. On heating, they do not soften; instead, they decompose because the strong cross-links prevent molecular movement.

    Thermoplastic polymers have linear or slightly branched chains with weaker intermolecular forces. Therefore, they soften on heating and can be reshaped.

Section BAttempt any three of the following: 7 x 3 = 21
  • a
    If a bulk material is optically transparent, will its nanomaterial counterpart also be transparent? Justify with an example
  • b
    Two enantiomers of a drug have different half-lives in the body . Explain the biochemical basis for this phenomenon
  • c
    How can the 12 Principles of Green Chemistry be applied to cement production to reduce environmental impact?
  • d
    Why is natural gas preferred over coal for power generation, ev en though coal 4 2 is more abundant? Two coal samples have identical fixed carbon content but different volatile matter percen tages. How will this affect the ir combustion properties?
  • e
    Discuss the primary degradation mechanisms that affect polymer stability in different environmental conditions
Section CAttempt any one part of the following: 07 x 1 = 07
  • a
    A hypothetical molecule X 2 has a bond order of 2.5. Propose possible charge states or electronic configurations for this molecule
  • b
    Given that paracetamol can be syn thesized via both conventional and green routes, what challenges exist in fully replacing the convention al method with the green method?
  • a
    How can a combination of UV, IR, and NMR spectroscopy be used t o determine the structure of an unknown organic compound? Illustr ate with an example
  • b
    A compound has the molecular formula C₄H₈O₂. It shows a singlet at 3.8 ppm and a quartet at 1.2 ppm in its ¹H NMR spectrum. Predict its st ructure and justify your answer
  • a
    Why does Portland cement contain both tri-calcium aluminate and di-calcium silicate, even though their hydration rates are vastly differen t? The hydration of cement releases heat, yet adding excess water weakens concrete. Explain the paradox
  • b
    Brass exposed to seawater loses zinc over time, leaving behind a copper-rich structure. Explain the underlying electrochemical process
  • a
    Why is the Zeolite process unsuita ble for water containing high concentrations of iron and manganese?A 500 L water sample requires 50 mL of 0.01 M EDTA to completely react with its calcium and magnesium ions. Calcul ate the total hardness in ppm as CaCO3
  • b
    i . C a n h y d r o g e n b e c l a s s i f i e d a s b o t h a p r i m a r y f u e l a n d a s e c ondary fuel? Justify your answer. ii. A fuel with a GCV of 35 MJ/kg has an NCV of 32 MJ/kg. Explain why there is a difference and how to calculate it
  • a
    Why is it necessary to perform the preparation of Grignard r eagents under anhydrous conditions?If 5.0 g of methylmagnesium bromide is rea cted with an excess of benzaldehyde, how much benzyl alcohol (C₆H₅CH₂OH) is expected, assuming 85% yield?
  • b
    Ex pl a i n w h y w a t er a nd oi l s d o n ot a dh e re t o T e fl o n . H ow d oe s this property make it suitable for non-stick co okware and industrial applicat ions? A piece of Teflon has a mass of 250 g and a density of 2.2 g/cm³. Calculate its volume

Question text is extracted from the official AKTU question paper PDF above. Check the original PDF for equations, diagrams and complete wording. Extracted: 2026-08-23.